Introduction to macromolecules

1.3 Introduction to Macromolecules

Summary

Biological macromolecules are polymers assembled from monomer subunits through dehydration synthesis, a reaction that removes water and forms a covalent bond between adjacent monomers. Repeating this reaction many times — polymerization — produces the large molecules cells need for structure, energy storage, and information.

Key Definition

Hydrolysis consumes a water molecule to break the covalent bond between monomers, splitting the hydrogen ion onto one monomer and the hydroxyl group onto the other, thereby dismantling polymers into their building blocks.

Together, these two reactions form a reversible system that cells use to build up and break down macromolecules as needed.

Dehydration Synthesis

  • Dominates during growth and biosynthesis

Hydrolysis

  • Dominates during digestion and molecular recycling

Both reactions center on covalent bonds and water, but they operate in opposite directions — a symmetry that AP exam questions frequently test by asking students to compare the two side by side, specifying bond changes and the precise fate of the water molecule.