Proteins

1.7 Proteins

Summary

Key Definition

Proteins are polymers of amino acids joined by covalent peptide bonds formed through dehydration synthesis between a carboxyl group and an amine group.

Each amino acid differs only in its R group, which can be hydrophobic, hydrophilic, or ionic. The chemical properties of these R groups drive the folding interactions that give each protein its unique shape — and therefore its unique function.

Key Definition

The specific linear sequence of amino acids constitutes the primary structure, which serves as the blueprint for all higher-order folding.

Secondary Structure

  • Arises from hydrogen bonds between backbone atoms

  • Producing alpha-helices and beta-pleated sheets

Tertiary Structure

  • Results from R-group interactions that fold the polypeptide into a three-dimensional shape

  • Hydrogen bonds

  • Hydrophobic interactions

  • Ionic interactions

  • Disulfide bridges

Quaternary Structure

  • Forms when multiple polypeptide subunits associate into a functional complex through the same types of interactions

All four structural levels work together to determine protein function, and disruption at any level can impair or destroy biological activity.

At a Glance

Structural Level Bonds / Interactions Result
Primary structure Covalent peptide bonds Specific linear sequence of amino acids
Secondary structure Hydrogen bonds between backbone atoms Alpha-helices and beta-pleated sheets
Tertiary structure Hydrogen bonds, hydrophobic interactions, ionic interactions, and disulfide bridges Three-dimensional shape
Quaternary structure The same types of interactions Multiple polypeptide subunits associate into a functional complex